UPSC MainsZOOLOGY-PAPER-I201115 Marks150 Words
Q13.

Give the mechanism of ozone degradation by chlorofluorocarbons.

How to Approach

The question requires a detailed explanation of the mechanism by which chlorofluorocarbons (CFCs) degrade the ozone layer. The answer should focus on the catalytic cycle involving chlorine atoms released from CFCs. A step-by-step explanation of the process, including the role of UV radiation, is crucial. The answer should be concise, sticking to the 150-word limit, and use scientific terminology accurately. Structure the answer by first introducing ozone depletion and then detailing the CFC-mediated degradation process.

Model Answer

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Introduction

The ozone layer, a region of Earth’s stratosphere, absorbs most of the Sun’s harmful ultraviolet (UV) radiation. Its depletion poses significant risks to life on Earth, including increased skin cancer rates and damage to ecosystems. Chlorofluorocarbons (CFCs), once widely used in refrigerants and aerosols, are major contributors to ozone depletion. These stable compounds, however, undergo a complex degradation process in the stratosphere, releasing chlorine atoms that catalytically destroy ozone molecules.

Mechanism of Ozone Degradation by CFCs

The degradation process unfolds in several steps:

  1. CFC Release & Transport: CFCs are released into the atmosphere and, due to their stability, slowly migrate to the stratosphere.
  2. UV Radiation Breakdown: In the stratosphere, high-energy UV radiation breaks down CFCs, releasing chlorine atoms (Cl). Cl + CFC → Cl + other products
  3. Catalytic Ozone Destruction: Chlorine atoms act as catalysts in a chain reaction:
    • Cl + O3 → ClO + O2 (Chlorine reacts with ozone, forming chlorine monoxide and oxygen)
    • ClO + O → Cl + O2 (Chlorine monoxide reacts with a single oxygen atom, regenerating chlorine and forming oxygen)
  4. Chain Reaction: The regenerated chlorine atom can then destroy another ozone molecule, repeating the cycle. A single chlorine atom can destroy thousands of ozone molecules.

This catalytic cycle continues until the chlorine atom is removed by reacting with other molecules, such as methane. Bromine atoms from halons also participate in a similar ozone-depleting process.

Conclusion

In conclusion, CFCs initiate a catalytic chain reaction in the stratosphere, leading to the destruction of ozone molecules. The release of chlorine atoms, triggered by UV radiation, is central to this process. International efforts, like the Montreal Protocol, have aimed to phase out CFCs to mitigate ozone depletion and protect the Earth from harmful UV radiation. Continued monitoring and adherence to these protocols are vital for ozone layer recovery.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Ozone Layer
A region of Earth’s stratosphere that absorbs most of the Sun’s ultraviolet (UV) radiation.
Catalytic Cycle
A series of chemical reactions in which a catalyst (like chlorine) participates, enabling the reaction to proceed more quickly without being consumed in the overall process.

Key Statistics

The Antarctic ozone hole reached a maximum extent of 22.7 million square kilometers in 2020.

Source: World Meteorological Organization (WMO), 2021

CFCs have atmospheric lifetimes ranging from 20 to over 100 years.

Source: Environmental Protection Agency (EPA), as of knowledge cutoff 2023

Examples

Montreal Protocol

An international treaty designed to protect the ozone layer by phasing out the production and consumption of ozone-depleting substances, including CFCs. It is widely considered one of the most successful environmental agreements.

Frequently Asked Questions

What are the alternatives to CFCs?

Hydrofluorocarbons (HFCs) were initially used as replacements for CFCs, but they are potent greenhouse gases. Newer alternatives include hydrofluoroolefins (HFOs) which have a much lower global warming potential.

Topics Covered

EcologyChemistryEnvironmental ChemistryAtmospheric PollutionOzone Layer