UPSC MainsGEOGRAPHY-PAPER-I201315 Marks250 Words
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Q7.

What are the characteristics that make CHC a serious threat to the ecosystem? Give examples.

How to Approach

This question requires a detailed understanding of Chlorofluorocarbons (CFCs) and their impact on the ecosystem. The answer should focus on the chemical properties of CFCs that make them harmful, their atmospheric behavior, and specific examples of ecological damage caused by them. Structure the answer by first defining CFCs, then detailing their characteristics as a threat, followed by specific examples of ecosystem impacts. Conclude with mitigation strategies and future concerns.

Model Answer

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Introduction

Chlorofluorocarbons (CFCs) are fully halogenated polyfluorocarbon compounds that were widely used as refrigerants, propellants, and solvents from the 1930s until the 1980s. Initially hailed for their stability and non-toxicity, their detrimental effects on the Earth’s stratosphere became apparent with the discovery of the ozone hole. These compounds pose a significant threat to the ecosystem due to their unique chemical and physical properties, leading to ozone depletion, climate change, and subsequent ecological disruptions. Understanding these characteristics is crucial for appreciating the severity of the environmental challenges they present.

Characteristics of CFCs as a Threat to the Ecosystem

CFCs are a serious threat to the ecosystem due to a combination of factors:

1. Chemical Stability and Atmospheric Lifetime

  • High Stability: CFCs are remarkably stable compounds, meaning they do not readily break down through chemical reactions in the lower atmosphere. This stability allows them to persist for extended periods.
  • Long Atmospheric Lifetime: This stability translates to exceptionally long atmospheric lifetimes, ranging from 20 to 120 years or even longer for some CFCs. This prolonged presence allows them to reach the stratosphere.

2. Ozone Depletion Potential (ODP)

  • UV Radiation Breakdown: In the stratosphere, CFCs are broken down by high-energy ultraviolet (UV) radiation. This breakdown releases chlorine atoms.
  • Catalytic Ozone Destruction: A single chlorine atom can catalytically destroy thousands of ozone molecules (O3). This process reduces the concentration of ozone in the stratosphere.
  • Ozone Layer Thinning: The thinning of the ozone layer increases the amount of harmful UV-B radiation reaching the Earth’s surface.

3. Global Warming Potential (GWP)

  • Greenhouse Gases: CFCs are potent greenhouse gases, meaning they trap heat in the Earth’s atmosphere, contributing to global warming.
  • High GWP Values: CFCs have significantly higher Global Warming Potentials (GWPs) than carbon dioxide (CO2). For example, CFC-12 has a GWP of approximately 10,900, meaning it traps 10,900 times more heat per molecule than CO2 over a 100-year period.

Examples of Ecosystem Impacts

1. Marine Ecosystems

  • Phytoplankton Damage: Increased UV-B radiation inhibits photosynthesis in phytoplankton, the base of the marine food web. This reduces primary productivity and impacts the entire marine ecosystem.
  • Damage to Fish Larvae: UV-B radiation can damage the DNA and early developmental stages of fish larvae, reducing their survival rates.
  • Coral Reef Bleaching: Increased UV-B radiation contributes to coral bleaching, weakening coral reefs and reducing biodiversity.

2. Terrestrial Ecosystems

  • Plant Damage: UV-B radiation can damage plant DNA, reduce plant growth, and alter plant physiology. This impacts agricultural yields and forest health.
  • Amphibian Decline: UV-B radiation can damage amphibian eggs and larvae, contributing to amphibian population declines.
  • Human Health Impacts: Increased UV-B radiation increases the risk of skin cancer, cataracts, and immune system suppression in humans.

3. Antarctic Ecosystem

The Antarctic ozone hole, a direct result of CFC emissions, has had profound impacts on the Antarctic ecosystem. Reduced phytoplankton populations have cascaded through the food web, affecting krill, fish, seals, and penguins. Studies have shown a correlation between ozone depletion and declines in Adelie penguin populations.

CFC Ozone Depletion Potential (ODP) Global Warming Potential (GWP) (100-year)
CFC-11 1.0 4,750
CFC-12 1.0 10,900
CFC-113 0.8 7,340

Conclusion

CFCs represent a stark example of how human activities can have far-reaching and detrimental consequences for the global ecosystem. While the Montreal Protocol (1987) has been remarkably successful in phasing out CFCs, their long atmospheric lifetimes mean that their effects will continue to be felt for decades to come. Continued monitoring of ozone levels, research into alternative refrigerants, and addressing climate change are crucial for mitigating the long-term impacts of these harmful chemicals and protecting the Earth’s ecosystems. The success of the Montreal Protocol demonstrates the power of international cooperation in addressing global environmental challenges.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Ozone Depletion Potential (ODP)
A relative measure of a chemical’s ability to deplete the ozone layer compared to CFC-11, which is assigned an ODP of 1.0.
Global Warming Potential (GWP)
A relative measure of how much heat a greenhouse gas traps in the atmosphere compared to carbon dioxide (CO2) over a specific time horizon (usually 100 years).

Key Statistics

The ozone layer is projected to recover to 1980 levels by around 2066-2075.

Source: World Meteorological Organization (WMO), 2023

CFCs accounted for approximately 8.6% of total greenhouse gas emissions in 1990, despite being phased out.

Source: IPCC, 1995 (Knowledge cutoff)

Examples

The Antarctic Ozone Hole

The annual Antarctic ozone hole, first discovered in 1985, is a dramatic example of CFC-induced ozone depletion. It expands significantly during the Antarctic spring (August-October), allowing increased levels of UV-B radiation to reach the surface.

Frequently Asked Questions

Are HCFCs and HFCs also harmful?

Hydrochlorofluorocarbons (HCFCs) are less damaging to the ozone layer than CFCs but still contribute to ozone depletion. Hydrofluorocarbons (HFCs) do not deplete the ozone layer but are potent greenhouse gases and are being phased down under the Kigali Amendment to the Montreal Protocol.

Topics Covered

GeographyEnvironmentChemistryPollutionEcosystemsChemicals