UPSC MainsZOOLOGY-PAPER-I201415 Marks
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Q27.

What is ozone layer? Describe the mechanism of degradation of ozone layer and its impact.

How to Approach

This question requires a detailed understanding of the ozone layer, its depletion mechanisms, and the resulting impacts. The answer should begin with a clear definition of the ozone layer and its importance. Then, a comprehensive explanation of the chemical processes leading to ozone depletion, focusing on the role of various pollutants, is crucial. Finally, the answer must cover the environmental and health consequences of ozone depletion. A structured approach, using headings and subheadings, will enhance clarity and readability.

Model Answer

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Introduction

The ozone layer, a region of Earth’s stratosphere containing high concentrations of ozone (O3), is vital for life on Earth. Discovered in 1913 by Charles Fabry, it absorbs the majority of the Sun’s harmful ultraviolet (UV) radiation, particularly UVB and UVC, preventing them from reaching the surface. However, since the 1970s, significant depletion of the ozone layer, particularly over Antarctica, has been observed, raising global concerns. This depletion is primarily caused by human-produced chemicals, leading to the ‘ozone hole’ and posing serious threats to human health and the environment.

Understanding the Ozone Layer

The ozone layer is located in the lower portion of the stratosphere, approximately 15 to 35 kilometers (9 to 22 miles) above Earth. Ozone is formed when UV radiation from the sun interacts with oxygen molecules (O2), splitting them into individual oxygen atoms (O) which then combine with other O2 molecules. This dynamic process of ozone creation and destruction maintains a natural balance. However, certain chemicals can disrupt this balance, leading to ozone depletion.

Mechanism of Ozone Layer Degradation

The degradation of the ozone layer is a complex process primarily driven by the release of man-made chemicals, particularly:

  • Chlorofluorocarbons (CFCs): Formerly widely used in refrigerants, aerosols, and solvents.
  • Halons: Used in fire extinguishers.
  • Carbon Tetrachloride: Used as a solvent.
  • Methyl Chloroform: Used as a solvent.
  • Nitrous Oxide (N2O): A byproduct of agricultural practices and industrial processes.

The Catalytic Cycle of Ozone Depletion

The depletion occurs through a catalytic cycle. Here’s a simplified explanation:

  1. Release of Halogens: CFCs and halons, being stable, reach the stratosphere. UV radiation breaks them down, releasing chlorine and bromine atoms.
  2. Catalytic Destruction: Chlorine and bromine atoms act as catalysts in the destruction of ozone. A single chlorine atom can destroy thousands of ozone molecules.
    • Cl + O3 → ClO + O2
    • ClO + O → Cl + O2
    The chlorine atom is regenerated, allowing it to continue the cycle. Bromine atoms are even more effective at destroying ozone than chlorine atoms.
  3. Polar Vortex & Ozone Hole: Over Antarctica, during the winter, a strong circulating wind pattern called the polar vortex isolates the air mass. This leads to the formation of polar stratospheric clouds (PSCs). PSCs provide surfaces for chemical reactions that convert inactive chlorine reservoirs into active chlorine radicals, accelerating ozone depletion when sunlight returns in the spring.

Impact of Ozone Layer Depletion

Environmental Impacts

  • Increased UV Radiation: Higher levels of UVB radiation reaching the Earth's surface.
  • Damage to Marine Ecosystems: UVB radiation harms phytoplankton, the base of the marine food web, impacting fisheries and marine biodiversity.
  • Reduced Plant Growth: UVB radiation can damage plant DNA and inhibit photosynthesis, reducing crop yields and forest productivity.
  • Material Degradation: Increased UV radiation accelerates the degradation of plastics, rubber, and other materials.

Human Health Impacts

  • Skin Cancer: Increased risk of melanoma and other types of skin cancer.
  • Cataracts: UVB radiation contributes to the development of cataracts, a clouding of the eye's lens.
  • Weakened Immune System: UVB radiation can suppress the immune system, making individuals more susceptible to infections.
  • Premature Aging of Skin: Increased wrinkles and loss of skin elasticity.

International Efforts & Mitigation

The Montreal Protocol (1987), an international treaty designed to protect the ozone layer by phasing out the production and consumption of ozone-depleting substances, is considered one of the most successful environmental agreements ever. Amendments to the Montreal Protocol have accelerated the phase-out of these substances. However, the long atmospheric lifetimes of these chemicals mean that full recovery of the ozone layer is expected to take decades. Furthermore, the increasing concentrations of nitrous oxide, which is not controlled by the Montreal Protocol, pose a continuing threat.

Conclusion

The ozone layer is a critical shield protecting life on Earth from harmful UV radiation. While the Montreal Protocol has been remarkably successful in mitigating ozone depletion, continued monitoring and adherence to the protocol are essential. Addressing the challenge of nitrous oxide emissions and understanding the long-term effects of climate change on the stratosphere remain crucial for ensuring the full recovery of the ozone layer and safeguarding the planet for future generations.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

UVB Radiation
Ultraviolet B (UVB) radiation is a type of electromagnetic radiation emitted by the sun. It has a shorter wavelength than UVA radiation and is more harmful to living organisms, causing DNA damage and increasing the risk of skin cancer.
Polar Stratospheric Clouds (PSCs)
Polar Stratospheric Clouds are clouds that form in the winter polar stratosphere at altitudes of 15–25 km. They are composed of ice crystals and play a crucial role in the catalytic destruction of ozone in the Antarctic ozone hole.

Key Statistics

The Antarctic ozone hole has, at times, reached a size of over 22.8 million square kilometers (8.8 million square miles).

Source: World Meteorological Organization (WMO), 2023

As of 2023, atmospheric levels of many key ozone-depleting substances have declined by over 99% from their peak levels.

Source: United Nations Environment Programme (UNEP), 2023 (Knowledge Cutoff)

Examples

The Antarctic Ozone Hole

The most prominent example of ozone depletion is the annual ozone hole that forms over Antarctica during the spring (August-October). This hole is caused by the unique atmospheric conditions over Antarctica, combined with the presence of ozone-depleting substances.

Frequently Asked Questions

Is the ozone layer recovering?

Yes, the ozone layer is showing signs of recovery, particularly in the upper stratosphere. This is largely due to the success of the Montreal Protocol in phasing out ozone-depleting substances. However, full recovery to pre-1980 levels is not expected until around 2060-2070.

Topics Covered

EnvironmentEcologyAtmospherePollutionClimate Change