UPSC MainsAGRICULTURE-PAPER-II201510 Marks150 Words
Q3.

What are Enzymes? Write the properties and factors affecting enzyme's activity.

How to Approach

This question requires a concise explanation of enzymes, their properties, and factors affecting their activity. The approach should be to first define enzymes and their role as biological catalysts. Then, systematically list their key properties (specificity, catalytic power, sensitivity) followed by factors like temperature, pH, substrate concentration, and inhibitors. A structured format with clear headings and bullet points will enhance readability and demonstrate a comprehensive understanding. The word limit necessitates brevity and precision.

Model Answer

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Introduction

Enzymes are biological catalysts, predominantly proteins, that accelerate biochemical reactions within living organisms. They are crucial for a vast array of processes, from digestion to DNA replication. The term "enzyme" was coined by Justus von Liebig in 1837. Without enzymes, these reactions would occur too slowly to sustain life. Recent advances in biotechnology are increasingly leveraging enzyme technology for industrial applications, including biofuel production and food processing, highlighting their growing importance. This response will detail enzyme properties and the factors influencing their activity.

What are Enzymes?

Enzymes are typically globular proteins that act as biological catalysts. They lower the activation energy required for a reaction to proceed, thereby increasing the reaction rate. Enzymes possess remarkable specificity, meaning each enzyme typically catalyzes a single type of reaction or a set of closely related reactions.

Properties of Enzymes

  • Specificity: Enzymes exhibit remarkable specificity, often binding to a single substrate due to the unique shape of their active site. This is often described by the "lock and key" model, though a more dynamic "induced fit" model is now generally accepted.
  • Catalytic Power: Enzymes can increase reaction rates by a factor of millions. For example, urease can catalyze the hydrolysis of urea over 106 times faster than the uncatalyzed reaction.
  • Sensitivity: Enzymes are highly sensitive to environmental conditions such as temperature and pH. Extreme conditions can denature the enzyme, rendering it inactive.
  • Colloidal Nature: Enzymes are colloidal in nature and can be precipitated by substances like alcohol or ammonium sulfate.
  • Proteinous Nature: Most enzymes are proteins. However, some RNA molecules, known as ribozymes, also exhibit catalytic activity.

Factors Affecting Enzyme Activity

Several factors influence the rate at which enzymes catalyze reactions:

1. Temperature

Enzyme activity generally increases with temperature up to a certain point. Beyond the optimum temperature (typically between 30°C and 40°C for human enzymes), the enzyme denatures, losing its catalytic activity. Psychrophilic enzymes (found in cold-loving organisms) have lower optimal temperatures.

2. pH

Each enzyme has an optimal pH range at which it functions most effectively. Deviations from this optimal pH can disrupt the enzyme's structure and alter its activity. For example, pepsin, an enzyme in the stomach, functions optimally at pH 2, while trypsin, found in the small intestine, functions best at pH 8.

3. Substrate Concentration

As substrate concentration increases, the reaction rate increases until it reaches a maximum (Vmax). Beyond Vmax, increasing substrate concentration has little effect on the reaction rate, as all enzyme molecules are saturated with substrate.

4. Enzyme Concentration

Generally, increasing enzyme concentration increases the reaction rate, assuming there's sufficient substrate available.

5. Inhibitors

Inhibitors are substances that reduce enzyme activity. They can be:

  • Competitive Inhibitors: Bind to the active site, blocking substrate binding.
  • Non-Competitive Inhibitors: Bind to a different site on the enzyme, altering its shape and reducing its activity.

6. Activators

Activators are substances that increase enzyme activity. Some metal ions, like magnesium (Mg2+), can act as enzyme activators.

Factor Effect on Enzyme Activity
Temperature Increases up to optimum, then decreases due to denaturation.
pH Optimal pH range for maximum activity.
Substrate Concentration Increases rate up to Vmax.

Conclusion

In conclusion, enzymes are essential biological catalysts that facilitate life-sustaining biochemical reactions. Their activity is governed by a delicate interplay of factors, including temperature, pH, substrate concentration, and the presence of inhibitors or activators. Understanding these factors is crucial not only for comprehending biological processes but also for harnessing enzyme technology in diverse fields, from medicine to industrial biotechnology. Future research focuses on developing more robust and efficient enzymes for various applications.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Active Site
The specific region on an enzyme where the substrate binds and catalysis occurs. Its shape is complementary to the substrate.
Denaturation
The process by which an enzyme loses its three-dimensional structure and, consequently, its catalytic activity, often due to heat or changes in pH.

Key Statistics

A single enzyme molecule can catalyze up to thousands of reactions per second.

Source: General Biochemistry Textbooks

The global enzyme market was valued at approximately $9.8 billion in 2022 and is projected to reach $13.7 billion by 2029.

Source: Fortune Business Insights

Examples

Lactase Deficiency

Lactase deficiency, or lactose intolerance, occurs when the enzyme lactase, which breaks down lactose, is deficient. This leads to digestive discomfort.

Frequently Asked Questions

What is the difference between the lock and key model and the induced fit model?

The lock and key model proposes a rigid enzyme structure. The induced fit model suggests the enzyme's active site changes shape to better accommodate the substrate.

Topics Covered

BiologyBiochemistryBotanyEnzymesPlant PhysiologyBiochemical Reactions