UPSC MainsGEOLOGY-PAPER-II201510 Marks
Q22.

Which one of the two minerals, magnetite and hematite, contains more iron? Illustrate by calculating iron concentration (in wt.%) of magnetite and hematite. Atomic weight of Fe = 56, O = 16.

How to Approach

This question requires a basic understanding of mineral chemistry and stoichiometric calculations. The approach should involve writing the chemical formulas for magnetite and hematite, calculating their molecular weights, and then determining the weight percentage of iron in each. A clear, step-by-step calculation is crucial. The answer should directly compare the iron concentration in both minerals, stating which one contains more iron.

Model Answer

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Introduction

Iron is one of the most abundant elements in the Earth’s crust and is a crucial component of many minerals. Magnetite (Fe₃O₄) and hematite (Fe₂O₃) are two of the most important iron ores, serving as primary sources for iron production. While both contain iron, their chemical compositions differ, leading to variations in their iron content. Determining the weight percentage of iron in each mineral is essential for evaluating their economic viability and understanding their geological significance. This answer will calculate and compare the iron concentration in magnetite and hematite using their respective chemical formulas and atomic weights.

Chemical Formulas and Molecular Weights

First, let's establish the chemical formulas and calculate the molecular weights of magnetite and hematite.

Magnetite (Fe₃O₄)

The chemical formula for magnetite is Fe₃O₄. To calculate its molecular weight:

  • Atomic weight of Fe = 56
  • Atomic weight of O = 16
  • Molecular weight of Fe₃O₄ = (3 x 56) + (4 x 16) = 168 + 64 = 232

Hematite (Fe₂O₃)

The chemical formula for hematite is Fe₂O₃. To calculate its molecular weight:

  • Atomic weight of Fe = 56
  • Atomic weight of O = 16
  • Molecular weight of Fe₂O₃ = (2 x 56) + (3 x 16) = 112 + 48 = 160

Calculating Iron Concentration (wt.%)

Now, we will calculate the weight percentage of iron in each mineral.

Magnetite (Fe₃O₄)

Weight of iron in one molecule of Fe₃O₄ = 3 x 56 = 168

Iron concentration (wt.%) = (Weight of iron / Molecular weight of Fe₃O₄) x 100

Iron concentration (wt.%) = (168 / 232) x 100 ≈ 72.37%

Hematite (Fe₂O₃)

Weight of iron in one molecule of Fe₂O₃ = 2 x 56 = 112

Iron concentration (wt.%) = (Weight of iron / Molecular weight of Fe₂O₃) x 100

Iron concentration (wt.%) = (112 / 160) x 100 = 70%

Comparison

Based on the calculations:

Mineral Iron Concentration (wt.%)
Magnetite (Fe₃O₄) 72.37%
Hematite (Fe₂O₃) 70%

Therefore, magnetite contains more iron (72.37%) than hematite (70%) by weight.

Conclusion

In conclusion, through stoichiometric calculations based on their chemical formulas and atomic weights, we have determined that magnetite (Fe₃O₄) possesses a higher iron concentration (approximately 72.37%) compared to hematite (Fe₂O₃) which has an iron concentration of 70%. This difference in iron content is a significant factor in evaluating the economic viability of these minerals as iron ores. Understanding the chemical composition of minerals is fundamental to geological and metallurgical studies.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Ore Mineral
An ore mineral is a mineral that contains a valuable metallic element or elements that can be profitably extracted.
Stoichiometry
Stoichiometry is the branch of chemistry that deals with the quantitative relationships between reactants and products in chemical reactions.

Key Statistics

India holds about 31.18% of the world’s total iron ore reserves as of 2022.

Source: Ministry of Mines, Annual Report 2022-23

China is the world’s largest producer and consumer of iron ore, accounting for over 60% of global demand (as of 2023).

Source: World Steel Association, 2023 data

Examples

Banded Iron Formations (BIFs)

Banded Iron Formations are sedimentary rocks consisting of alternating layers of iron oxides (like hematite and magnetite) and chert. They are major sources of iron ore globally, particularly in Australia and India.

Frequently Asked Questions

What factors influence the economic viability of iron ore deposits?

Factors include the iron content of the ore, the ease of extraction, transportation costs, and global market prices for iron.