UPSC MainsGEOLOGY-PAPER-II201810 Marks
Q17.

What are the types of samples collected and analysed in geochemical exploration programmes? Which one of these samples is generally preferred and why is it preferred?

How to Approach

This question requires a detailed understanding of geochemical exploration techniques. The answer should begin by defining geochemical exploration and outlining the different types of samples collected. It should then focus on stream sediment samples, explaining why they are generally preferred over other sample types, considering factors like cost-effectiveness, representativeness, and ease of collection. The answer should also briefly mention the analytical techniques used on these samples. A structured approach, categorizing sample types and their pros/cons, will be beneficial.

Model Answer

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Introduction

Geochemical exploration is a crucial component of mineral exploration, involving the systematic measurement of chemical composition of naturally occurring materials to identify anomalies indicative of ore deposits. It relies on the principle that ore-forming processes often leave a ‘halo’ of altered or enriched elements in the surrounding environment. The success of geochemical exploration hinges on the appropriate selection and analysis of samples. Various types of samples are collected during geochemical surveys, each with its own advantages and limitations. This answer will detail these sample types and explain why stream sediment samples are generally preferred in geochemical exploration programmes.

Types of Samples Collected in Geochemical Exploration

Geochemical exploration programs utilize a variety of sample types, broadly categorized as follows:

1. Stream Sediment Samples

These are collected from active stream beds, typically focusing on the fine-grained sediment (silt and clay fractions) deposited in the stream channel. They are relatively inexpensive to collect and analyze, and represent a broad drainage area, integrating geochemical signals from various sources.

  • Advantages: Cost-effective, large area coverage, integrates geochemical signals.
  • Disadvantages: Can be affected by recent erosion, contamination from upstream activities, and dilution effects.

2. Soil Samples

Soil samples are collected from the surface or shallow subsurface (typically up to 1 meter depth). They are often collected on a grid pattern and are useful for detecting local geochemical anomalies. Different soil horizons may be sampled to understand weathering profiles.

  • Advantages: Provides localized geochemical information, less affected by dilution than stream sediments.
  • Disadvantages: More expensive and time-consuming to collect than stream sediments, can be affected by soil development processes and contamination.

3. Rock Samples (Rock Chips/Outcrops)

Rock samples are collected directly from outcrops or rock chips from weathered surfaces. They provide direct information about the composition of the bedrock. These are particularly useful in areas with limited soil or sediment cover.

  • Advantages: Direct representation of bedrock composition, useful in areas with sparse vegetation.
  • Disadvantages: Limited spatial coverage, can be difficult to access outcrops, susceptible to weathering alteration.

4. Vegetation Samples (Plant Tissue/Bio-geochemical)

Plant tissues (leaves, bark, roots) can accumulate trace elements from the soil and groundwater. This method is particularly useful in areas with thick vegetation cover or where other sampling methods are difficult.

  • Advantages: Useful in areas with dense vegetation, can detect deep-seated mineralization.
  • Disadvantages: Element uptake varies with plant species and physiological factors, requires careful calibration.

5. Water Samples

Surface and groundwater samples are analyzed for dissolved ions and trace elements. They can provide information about the regional geochemical background and identify areas of anomalous metal concentrations.

  • Advantages: Relatively inexpensive, provides regional geochemical information.
  • Disadvantages: Low concentrations of many elements, susceptible to contamination, affected by hydrological conditions.

Why Stream Sediment Samples are Generally Preferred

Stream sediment samples are generally preferred for regional geochemical exploration due to a combination of factors:

  • Cost-Effectiveness: Stream sediment sampling is significantly cheaper and faster than other methods like soil or rock sampling, allowing for broader area coverage with limited resources.
  • Representativeness: Stream sediments integrate geochemical signals from a large drainage basin, providing a regional overview of the geochemical landscape. This integration helps to identify broad anomalies that warrant further investigation.
  • Ease of Collection: Stream sediments are relatively easy to collect, requiring minimal specialized equipment or training.
  • Detection of Anomalies: They are effective in detecting anomalies associated with both near-surface and deeper mineralization, as weathering and erosion processes transport elements downstream.

While stream sediments have limitations (dilution, contamination), these can be mitigated through careful sampling design, appropriate sample preparation techniques (sieving, drying), and the use of multi-element analysis. Analytical techniques commonly employed include Atomic Absorption Spectrometry (AAS), Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES), and Inductively Coupled Plasma Mass Spectrometry (ICP-MS).

Sample Type Cost Area Coverage Ease of Collection Representativeness
Stream Sediment Low High High Regional
Soil Medium Medium Medium Localized
Rock High Low Low Bedrock Specific
Vegetation Medium Medium Medium Plant Specific
Water Low High High Regional

Conclusion

In conclusion, geochemical exploration relies on a diverse range of sampling techniques, each suited to specific geological settings and exploration objectives. While all sample types contribute valuable information, stream sediment sampling remains the preferred method for initial regional surveys due to its cost-effectiveness, broad area coverage, and ability to integrate geochemical signals from a large drainage basin. Subsequent exploration phases often incorporate other sampling methods to refine anomalies and pinpoint potential ore deposits. The integration of geochemical data with geological mapping, geophysical surveys, and remote sensing data is crucial for successful mineral exploration.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Geochemical Anomaly
A significant deviation in the concentration of a chemical element or group of elements from the established background level in a given geological environment, potentially indicating the presence of an ore deposit.
Inductively Coupled Plasma Mass Spectrometry (ICP-MS)
A highly sensitive analytical technique used in geochemical analysis to determine the concentration of a wide range of elements in a sample by ionizing the sample and measuring the mass-to-charge ratio of the resulting ions.

Key Statistics

Global exploration spending reached $12.3 billion in 2022, with a significant portion allocated to geochemical surveys (approximately 15-20%).

Source: S&P Global Market Intelligence, 2023

The cost of geochemical exploration can range from $5 to $50 per sample, depending on the sampling density, analytical techniques used, and accessibility of the area. (Data as of 2020)

Source: Exploration Insights, 2020

Examples

The Voisey’s Bay Nickel Deposit, Canada

Discovered in 1995, Voisey’s Bay was initially identified through regional stream sediment surveys that revealed anomalous nickel and copper concentrations in drainage systems. Follow-up soil and rock sampling confirmed the presence of a significant magmatic nickel-copper-cobalt deposit.

Frequently Asked Questions

What is the role of sample preparation in geochemical analysis?

Sample preparation is critical for ensuring accurate and reliable geochemical data. It typically involves drying, crushing, grinding, sieving, and sometimes chemical digestion to liberate the elements of interest and prepare the sample for analysis.

Topics Covered

GeologyEconomic GeologyGeochemical ExplorationSampling TechniquesMineral Exploration