UPSC MainsGEOLOGY-PAPER-II201810 Marks
Q2.

Explain the symmetry elements in a stereogram of general form {hkil} in the hexagonal-scalenohedral class.

How to Approach

This question requires a detailed understanding of crystal symmetry and its representation in stereograms, specifically within the hexagonal-scalenohedral class. The answer should begin by defining a stereogram and symmetry elements. Then, it should systematically identify and explain each symmetry element present in the {hkil} stereogram of this class – including the principal axis, diad axes, plane of symmetry, and center of symmetry – with clear explanations of their orientation and effect on the form. A diagrammatic representation, though not explicitly asked for, would significantly enhance the answer.

Model Answer

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Introduction

A stereogram is a graphical representation of crystal faces, projected onto a plane, providing a visual depiction of the crystal's morphology and symmetry. Understanding the symmetry elements within a stereogram is crucial for identifying and classifying minerals. The hexagonal-scalenohedral class, a subgroup of the hexagonal system, is characterized by a unique combination of symmetry elements. This class exhibits a single 6-fold rotation axis, along with other symmetry elements that define its specific form. The general form {hkil} represents a combination of prism and pyramid faces, and analyzing its symmetry reveals the underlying crystallographic structure.

Understanding Symmetry Elements

Symmetry elements are geometric entities (points, lines, or planes) about which symmetry operations can be performed on a crystal without altering its appearance. These operations include rotation, reflection, inversion, and glide reflection. The presence and arrangement of these elements define a crystal's symmetry class.

Symmetry Elements in the Hexagonal-Scalenohedral Class

The hexagonal-scalenohedral class (6/mmm) possesses the following symmetry elements, which are reflected in the stereogram of the general form {hkil}:

1. Principal Axis of Symmetry (6-fold)

This is the most prominent symmetry element, denoted as a 6-fold rotation axis. It passes through the apex of the hexagonal prism and the center of the hexagonal base. Rotating the crystal 60° (360°/6) around this axis results in an identical view. In the stereogram, this is represented by the six equivalent prism faces.

2. Diad Axes of Symmetry (3-fold)

There are three 2-fold (diad) axes of symmetry perpendicular to the principal axis. These axes bisect the angles between the prism faces. Rotating the crystal 180° around each of these axes results in an identical view. In the stereogram, these are represented by the symmetry of the pyramid faces relative to the prism faces.

3. Planes of Symmetry

The hexagonal-scalenohedral class has six vertical mirror planes (planes of symmetry). These planes contain the principal axis and bisect the angles between adjacent prism faces. Reflecting the crystal across any of these planes results in an identical view. In the stereogram, these planes are evident in the symmetrical arrangement of the prism and pyramid faces around the principal axis.

4. Center of Symmetry

A center of symmetry exists at the geometric center of the crystal. An inversion through this center transforms any point (x, y, z) to (-x, -y, -z). This means that for every face, there is an equivalent face located directly opposite the center. In the stereogram, this is manifested by the symmetrical arrangement of faces on either side of the center.

Analyzing the {hkil} Stereogram

The general form {hkil} in the hexagonal-scalenohedral class combines prism faces (hk00) and pyramid faces (hkil). The symmetry elements dictate the arrangement of these faces:

  • The six prism faces (hk00) are symmetrically arranged around the 6-fold axis.
  • The pyramid faces (hkil) are arranged in a manner consistent with the three 2-fold axes and the six mirror planes.
  • The center of symmetry ensures that for every pyramid face, there is a corresponding face on the opposite side of the center.

The specific values of h, k, i, and l determine the relative sizes and shapes of the prism and pyramid faces, but the overall symmetry remains consistent with the hexagonal-scalenohedral class.

Symmetry Element Operation Effect on {hkil} Stereogram
6-fold Rotation Axis Rotation by 60° Six equivalent prism faces
3-fold Diad Axes Rotation by 180° Symmetry of pyramid faces
Mirror Planes Reflection Symmetrical arrangement of faces
Center of Symmetry Inversion Faces paired symmetrically around the center

Conclusion

In conclusion, the stereogram of the general form {hkil} in the hexagonal-scalenohedral class exhibits a high degree of symmetry due to the presence of a 6-fold rotation axis, three 2-fold axes, six mirror planes, and a center of symmetry. Understanding these symmetry elements is fundamental to identifying and classifying minerals belonging to this crystal class. The arrangement of prism and pyramid faces within the stereogram directly reflects the influence of these symmetry operations, providing a visual representation of the underlying crystallographic structure.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Stereogram
A stereographic projection of crystal faces onto a plane, used to visualize the crystal's morphology and symmetry.
Hermann-Mauguin Symbol
A shorthand notation used to represent the symmetry elements of a crystal class, such as 6/mmm for the hexagonal-scalenohedral class.

Key Statistics

The hexagonal crystal system comprises approximately 10% of all known minerals (as of 2020).

Source: Mindat.org (knowledge cutoff 2023)

Approximately 20% of known minerals exhibit hexagonal symmetry (as of 2018).

Source: International Mineralogical Association (IMA) database (knowledge cutoff 2023)

Examples

Quartz

Quartz (SiO2) is a prominent example of a mineral belonging to the hexagonal-scalenohedral class, exhibiting the described symmetry elements in its crystal form.

Frequently Asked Questions

What is the difference between a crystal system and a crystal class?

A crystal system is a broader categorization based on the axes lengths and angles, while a crystal class is a subgroup within a system defined by specific symmetry elements.

Topics Covered

GeologyMineralogyCrystallographySymmetryMineral Identification