UPSC MainsZOOLOGY-PAPER-I201920 Marks
Q20.

What is Biogeochemical cycle? Discuss in detail the Nitrogen cycle.

How to Approach

This question requires a two-pronged approach. First, define biogeochemical cycles and explain their significance. Then, dedicate the majority of the answer to a detailed discussion of the nitrogen cycle, covering its various stages, the microorganisms involved, and human impacts. Structure the answer by first defining the broader concept, then breaking down the nitrogen cycle into its key processes (nitrogen fixation, ammonification, nitrification, denitrification) with specific examples. Include diagrams where appropriate to enhance understanding. Focus on the ecological and environmental importance of the cycle.

Model Answer

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Introduction

Biogeochemical cycles are pathways for the circulation of chemical elements in biotic and abiotic compartments of Earth. These cycles are essential for life, ensuring the continuous availability of nutrients required by organisms. They involve biological, geological, and chemical processes, hence the name ‘biogeochemical’. Understanding these cycles is crucial in the context of environmental science, particularly with increasing anthropogenic impacts on natural ecosystems. The nitrogen cycle, a vital component of these cycles, is particularly important as nitrogen is a key building block of proteins and nucleic acids, and often a limiting nutrient in many ecosystems.

What is a Biogeochemical Cycle?

Biogeochemical cycles describe the movement of essential elements – such as carbon, nitrogen, phosphorus, sulfur, and water – through the Earth’s atmosphere, lithosphere, hydrosphere, and biosphere. These cycles are driven by both biotic (living organisms) and abiotic (non-living) factors. They ensure that these elements are continuously recycled, allowing for their sustained availability to support life. Disruptions to these cycles, often caused by human activities, can have significant ecological consequences.

The Nitrogen Cycle: A Detailed Discussion

The nitrogen cycle is a complex process involving multiple stages and a diverse range of microorganisms. Atmospheric nitrogen (N2), though abundant (approximately 78% of the atmosphere), is largely unusable by most organisms. The cycle converts this inert nitrogen into forms that can be utilized by plants and animals.

1. Nitrogen Fixation

This is the process of converting atmospheric nitrogen (N2) into ammonia (NH3) or ammonium (NH4+). This can occur through three main pathways:

  • Biological Nitrogen Fixation: Carried out by nitrogen-fixing bacteria, such as Rhizobium (symbiotic relationship with leguminous plants like soybeans and peas) and Azotobacter (free-living bacteria in soil). These bacteria possess the enzyme nitrogenase, which catalyzes the conversion.
  • Atmospheric Fixation: Lightning provides the energy to convert N2 into nitrogen oxides (NOx), which are then carried to the earth's surface by precipitation.
  • Industrial Fixation: The Haber-Bosch process, developed in the early 20th century, industrially fixes nitrogen to produce ammonia for fertilizers.

2. Ammonification

When plants and animals die, or when animals excrete waste, the organic nitrogen compounds are broken down by decomposers (bacteria and fungi) into ammonia (NH3). This process is called ammonification. The ammonia is then converted to ammonium (NH4+) in the soil.

3. Nitrification

Nitrification is a two-step process carried out by nitrifying bacteria. First, Nitrosomonas bacteria convert ammonium (NH4+) into nitrite (NO2-). Then, Nitrobacter bacteria convert nitrite (NO2-) into nitrate (NO3-). Nitrate is the primary form of nitrogen absorbed by plants.

4. Denitrification

Denitrification is the process where nitrate (NO3-) is converted back into atmospheric nitrogen (N2) by denitrifying bacteria (e.g., Pseudomonas) under anaerobic conditions (e.g., waterlogged soils). This process completes the cycle, returning nitrogen to the atmosphere.

5. Assimilation

Plants absorb nitrate (NO3-) or ammonium (NH4+) from the soil through their roots. This nitrogen is then incorporated into organic molecules like amino acids, proteins, and nucleic acids – a process called assimilation. Animals obtain nitrogen by consuming plants or other animals.

Table summarizing the Nitrogen Cycle Stages:

Stage Process Microorganisms Involved Input Output
Nitrogen Fixation Conversion of N2 to NH3/NH4+ Rhizobium, Azotobacter, Atmospheric processes, Industrial processes N2 NH3/NH4+
Ammonification Decomposition of organic matter to NH3/NH4+ Decomposers (bacteria & fungi) Organic Nitrogen NH3/NH4+
Nitrification Conversion of NH4+ to NO2- and NO3- Nitrosomonas, Nitrobacter NH4+ NO3-
Denitrification Conversion of NO3- to N2 Pseudomonas NO3- N2

Human Impacts on the Nitrogen Cycle: Excessive use of nitrogen fertilizers, industrial emissions, and burning of fossil fuels have significantly altered the nitrogen cycle. This has led to:

  • Eutrophication: Excess nitrogen runoff into waterways causes algal blooms, depleting oxygen levels and harming aquatic life.
  • Acid Rain: Nitrogen oxides contribute to acid rain, damaging forests and aquatic ecosystems.
  • Greenhouse Gas Emissions: Nitrous oxide (N2O), a byproduct of denitrification, is a potent greenhouse gas.

Conclusion

The biogeochemical cycles, particularly the nitrogen cycle, are fundamental to maintaining life on Earth. The nitrogen cycle’s intricate processes, driven by microbial activity, ensure the continuous availability of this essential nutrient. However, human activities have significantly disrupted this cycle, leading to various environmental problems. Sustainable agricultural practices, reduced fossil fuel consumption, and improved wastewater treatment are crucial for mitigating these impacts and preserving the integrity of the nitrogen cycle for future generations.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Eutrophication
The enrichment of a body of water with nutrients, typically nitrogen and phosphorus, leading to excessive plant growth and decay, oxygen depletion, and ultimately, the death of aquatic life.
Nitrogenase
An enzyme complex used by nitrogen-fixing bacteria and archaea to catalyze the conversion of atmospheric nitrogen (N<sub>2</sub>) into ammonia (NH<sub>3</sub>).

Key Statistics

Globally, human activities fix more nitrogen than all natural processes combined. Approximately 150 million tonnes of nitrogen are fixed industrially each year (as of 2018).

Source: FAO, 2018

Nitrous oxide (N<sub>2</sub>O) has a global warming potential 265-298 times that of carbon dioxide over a 100-year period (IPCC, 2021).

Source: IPCC, 2021

Examples

Gulf of Mexico Dead Zone

The Mississippi River carries excess nitrogen from agricultural runoff into the Gulf of Mexico, causing a large "dead zone" where oxygen levels are too low to support most marine life. This zone can cover an area larger than the state of New Jersey.

Frequently Asked Questions

What is the role of legumes in the nitrogen cycle?

Legumes have a symbiotic relationship with <em>Rhizobium</em> bacteria in their root nodules. These bacteria fix atmospheric nitrogen into ammonia, providing the plant with a usable form of nitrogen. In return, the plant provides the bacteria with carbohydrates and a protected environment.

Topics Covered

Environmental ScienceEcologyBiogeochemical Cycle, Nitrogen Cycle, Nitrogen Fixation, Denitrification