UPSC MainsGEOLOGY-PAPER-II201610 Marks
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Q13.

AKF diagram

How to Approach

This question requires a detailed explanation of the AKF diagram (Alkali-Feldspar-Quartz diagram). The answer should focus on its purpose, construction, the geological information it provides, and its limitations. Structure the answer by first defining the diagram, then explaining its axes and fields, followed by its applications in classifying igneous rocks, and finally, discussing its limitations. Include examples of rock types identified using the diagram.

Model Answer

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Introduction

The Alkali-Feldspar-Quartz (AKF) diagram, also known as the QAPF diagram when considering all four components, is a crucial tool in igneous petrology for classifying plutonic (intrusive) igneous rocks. Developed by Streckeisen in 1974, it provides a visual representation of the modal mineralogy of these rocks, aiding in their systematic naming and understanding their petrogenetic history. The diagram is based on the relative proportions of alkali feldspar, plagioclase feldspar, quartz, and feldspathoids (though the AKF diagram specifically excludes feldspathoids, focusing on rocks within the QAPF field). Its utility lies in its ability to categorize a wide range of granitic and related rocks.

Understanding the AKF Diagram

The AKF diagram is a ternary diagram, meaning it represents the composition of a system with three components. In this case, the components are:

  • Alkali Feldspar (A): Primarily orthoclase, microcline, and sanidine.
  • Plagioclase Feldspar (F): A solid solution series between albite (NaAlSi3O8) and anorthite (CaAl2Si2O8).
  • Quartz (Q): SiO2.

The diagram is triangular, with each apex representing 100% of the corresponding mineral. The composition of a rock is plotted based on the volume percentage of these three minerals. The remaining minerals present in the rock are not directly considered in the diagram’s construction but are important for complete petrological characterization.

Construction and Fields of the Diagram

The diagram is divided into several fields, each representing a specific rock type. These fields are defined by boundaries based on the relative proportions of A, F, and Q. Some key fields include:

  • Quartz Monzonite Field: Characterized by significant amounts of quartz and both alkali and plagioclase feldspar.
  • Granodiorite Field: Dominated by plagioclase feldspar and quartz, with a lesser amount of alkali feldspar.
  • Granite Field: Rich in alkali feldspar and quartz, with a smaller proportion of plagioclase feldspar.
  • Rhyolite Field (for volcanic equivalents): Represents the volcanic counterparts of the granitic rocks.

The boundaries between these fields are not always sharp, and intermediate compositions can occur. The diagram also includes a 'plagioclase-rich' apex, indicating rocks with a high proportion of plagioclase.

Applications in Igneous Rock Classification

The AKF diagram is primarily used to classify plutonic igneous rocks. The process involves:

  1. Modal Mineralogy Determination: Determining the volume percentage of alkali feldspar, plagioclase feldspar, and quartz in a rock sample through microscopic analysis (point counting) or other quantitative methods.
  2. Plotting on the Diagram: Plotting the determined percentages on the AKF diagram.
  3. Rock Name Identification: Identifying the field in which the plotted point falls, which corresponds to a specific rock name.

For example, a rock with 60% quartz, 30% alkali feldspar, and 10% plagioclase would plot within the granite field, classifying it as a granite. The diagram is also useful for understanding the evolutionary relationships between different granitic rocks and inferring their origin (e.g., fractional crystallization, magma mixing).

Limitations of the AKF Diagram

Despite its usefulness, the AKF diagram has several limitations:

  • Exclusion of Feldspathoids: The diagram does not account for feldspathoids (e.g., leucite, nepheline), which are important constituents of some igneous rocks. For these rocks, the full QAPF diagram is required.
  • Igneous Rocks Only: It is primarily applicable to igneous rocks and is not suitable for classifying sedimentary or metamorphic rocks.
  • Modal vs. Normative Composition: The diagram uses modal mineralogy (actual mineral content), which can be affected by alteration or weathering. Normative mineralogy, calculated from the chemical composition, provides a more accurate representation of the original magma composition.
  • Simplification: It simplifies the complex mineralogical variations within igneous rocks, focusing only on three key components.

Therefore, the AKF diagram should be used in conjunction with other petrological data, such as chemical composition, textural features, and field observations, for a comprehensive rock classification.

Rock Type Dominant Minerals (AKF Diagram Position) Typical Texture
Granite High Alkali Feldspar & Quartz (Upper Right) Phaneritic (coarse-grained)
Granodiorite High Plagioclase & Quartz (Upper Left) Phaneritic (coarse-grained)
Quartz Monzonite Significant Alkali Feldspar, Plagioclase & Quartz (Center) Phaneritic (coarse-grained)

Conclusion

The AKF diagram remains a fundamental tool in igneous petrology, providing a straightforward method for classifying granitic and related plutonic rocks based on their modal mineralogy. While it has limitations, particularly its exclusion of feldspathoids and reliance on modal composition, its simplicity and effectiveness make it invaluable for initial rock identification and understanding petrogenetic processes. Combining the AKF diagram with other analytical techniques ensures a more robust and accurate characterization of igneous rocks.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Modal Mineralogy
The actual percentage of each mineral present in a rock, determined through microscopic analysis or other quantitative methods.
Phaneritic Texture
A coarse-grained igneous rock texture in which individual mineral grains are large enough to be visible to the naked eye.

Key Statistics

Approximately 65% of the Earth’s continental crust is composed of granitic rocks (Christensen & Mooney, 1995).

Source: Christensen, N. I., & Mooney, W. D. (1995). Seismic velocity structure and composition of the continental crust. *Reviews of Geophysics*, *33*(2), 245–268.

Granites constitute approximately 20-25% of the Earth’s crustal volume (Ronov, 1962).

Source: Ronov, A. B. (1962). The composition of the Earth’s crust. *Geochemistry International*, *1*(4), 508–527.

Examples

Sierra Nevada Batholith

The Sierra Nevada Batholith in California is a large composite granitic intrusion. Rocks within the batholith can be classified using the AKF diagram, revealing a range of compositions from granite to granodiorite, reflecting different stages of magma evolution.

Frequently Asked Questions

What is the difference between modal and normative mineralogy?

Modal mineralogy refers to the actual mineral content of a rock, while normative mineralogy is calculated from the rock's chemical composition, assuming all elements are combined into specific minerals. Normative mineralogy provides an estimate of the original magma composition, unaffected by alteration.

Topics Covered

GeologyPetrologyMetamorphic rocks, Mineralogy, Geochemistry