UPSC MainsGEOLOGY-PAPER-II201610 Marks
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Q14.

In a mineral, the refractive indices are determined as ω = 1.548 and δ = 1.634. Calculate the birefringence of the mineral and comment on its optic nature.

How to Approach

This question tests the candidate's understanding of optical mineralogy, specifically birefringence and its relation to optic nature. The approach should involve first calculating birefringence using the given refractive indices. Then, based on the calculated value, the candidate should comment on whether the mineral is uniaxial or biaxial. A brief explanation of how birefringence relates to the mineral's structure and its impact on observed optical properties is crucial. The answer should demonstrate a clear understanding of the underlying principles.

Model Answer

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Introduction

Optical mineralogy is a crucial branch of petrology, utilizing the interaction of light with minerals to identify and characterize them. Refractive index, a fundamental optical property, describes how light bends when entering a mineral. Minerals can exhibit one or two refractive indices, leading to the concept of birefringence – the difference between the maximum and minimum refractive indices. This difference is a key indicator of a mineral’s crystal system and its optic nature, whether it is uniaxial or biaxial. Determining birefringence is essential for accurate mineral identification using a polarizing microscope.

Calculating Birefringence

Birefringence (Δ) is calculated as the difference between the maximum and minimum refractive indices. In this case, we are given ω (ordinary ray refractive index) = 1.548 and δ (extraordinary ray refractive index) = 1.634.

Therefore, Δ = δ - ω = 1.634 - 1.548 = 0.086

Optic Nature Determination

The calculated birefringence value of 0.086 allows us to comment on the mineral’s optic nature. Minerals are classified as either uniaxial or biaxial based on their birefringence and the number of optic axes.

Uniaxial Minerals

Uniaxial minerals belong to the tetragonal, hexagonal, or trigonal crystal systems. They have one optic axis and exhibit a single refractive index for light vibrating parallel to that axis. Birefringence in uniaxial minerals is generally lower, typically ranging from 0 to 0.020. Examples include calcite and aragonite.

Biaxial Minerals

Biaxial minerals belong to the orthorhombic, monoclinic, or triclinic crystal systems. They have two optic axes and exhibit two refractive indices for all directions of light vibration. Birefringence in biaxial minerals is generally higher, ranging from 0.020 to 0.090 or even higher. Examples include augite and hornblende.

Since the calculated birefringence (0.086) falls within the typical range for biaxial minerals (0.020 - 0.090), we can conclude that the mineral in question is biaxial.

Further Implications

The relatively high birefringence suggests a complex crystal structure with varying atomic arrangements that cause significant differences in the speed of light propagation in different directions. This also implies that the mineral will exhibit strong interference colors when observed under a polarizing microscope. Determining the exact biaxial angle (2V) would require further optical measurements, such as determining the optic sign (positive or negative).

Table Summarizing Optic Nature and Birefringence

Optic Nature Crystal System Optic Axes Typical Birefringence Range Examples
Uniaxial Tetragonal, Hexagonal, Trigonal One 0 - 0.020 Calcite, Aragonite
Biaxial Orthorhombic, Monoclinic, Triclinic Two 0.020 - 0.090+ Augite, Hornblende

Conclusion

In conclusion, the mineral with refractive indices ω = 1.548 and δ = 1.634 exhibits a birefringence of 0.086. This value strongly indicates that the mineral is biaxial, belonging to one of the orthorhombic, monoclinic, or triclinic crystal systems. Further optical analysis, including determining the optic sign and biaxial angle, would be necessary for complete mineral identification. Understanding birefringence is fundamental to interpreting the optical properties of minerals and their geological significance.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Refractive Index
The refractive index (n) is a dimensionless number that describes how light propagates through a material. It is defined as the ratio of the speed of light in a vacuum to the speed of light in the material.
Optic Axis
The optic axis is a direction in a crystal along which light travels with equal velocity regardless of its polarization. Uniaxial minerals have one optic axis, while biaxial minerals have two.

Key Statistics

The highest recorded birefringence is found in the mineral yttrium orthovanadate (YVO4), with a value exceeding 0.200 (as of 2023).

Source: Smith, R.L. (2023). Optical Mineralogy. Pearson Education.

Approximately 90% of rock-forming minerals are biaxial, highlighting the prevalence of this optic nature in Earth's crust (based on data from mineral databases as of 2022).

Source: Mindat.org (2022). Mineral Database.

Examples

Calcite and Double Refraction

Calcite (CaCO3) is a classic example of a uniaxial mineral exhibiting double refraction. When a transparent object is placed on a piece of calcite, it appears as two separate images due to the different refractive indices for the ordinary and extraordinary rays.

Frequently Asked Questions

What is the significance of optic sign?

Optic sign (positive or negative) indicates whether the extraordinary ray is faster or slower than the ordinary ray in a biaxial mineral. It is determined by the orientation of the optic axes and is crucial for identifying the mineral.

Topics Covered

GeologyMineralogyOptical properties, Crystal optics, Mineral analysis