UPSC MainsGEOLOGY-PAPER-II202410 Marks150 Words
Q18.

Discuss briefly about the abundance of elements in the Universe. State Oddo-Harkins rule with examples.

How to Approach

This question requires a concise yet comprehensive answer covering both the elemental abundance in the universe and the Oddo-Harkins rule. The approach should begin with a general overview of cosmic element distribution, highlighting the dominance of hydrogen and helium. Then, the Oddo-Harkins rule needs to be explained clearly with illustrative examples. Structure the answer into two distinct parts: abundance and the rule, ensuring clarity and conciseness within the 150-word limit. Focus on providing factual information and avoiding unnecessary details.

Model Answer

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Introduction

The universe is composed primarily of hydrogen and helium, formed during the Big Bang nucleosynthesis. Heavier elements are created through stellar nucleosynthesis and supernova explosions. Understanding the abundance of elements provides insights into the universe’s evolution and the processes governing element formation. The Oddo-Harkins rule, a fundamental principle in geochemistry, describes a systematic relationship between atomic number and isotopic abundance, offering clues about nuclear stability and formation pathways.

Elemental Abundance in the Universe

Hydrogen (H) constitutes approximately 71% of the universe’s mass, followed by Helium (He) at 27%. All other elements collectively make up only about 2%. This distribution is a direct consequence of the Big Bang and subsequent stellar processes. Trace amounts of elements like oxygen, carbon, nitrogen, iron, and silicon are crucial for planet formation and life.

Oddo-Harkins Rule

The Oddo-Harkins rule states that elements with even atomic numbers are more abundant than those with odd atomic numbers. Furthermore, even-numbered isotopes are generally more abundant than odd-numbered isotopes within an element. This is because even numbers of protons and neutrons lead to more stable nuclei due to increased nuclear binding energy.

Examples:

  • Silicon (Si, atomic number 14 - even): More abundant than Aluminum (Al, atomic number 13 - odd).
  • Oxygen (O, atomic number 8 - even): 16O is far more abundant than 17O.

This rule is a consequence of the nuclear forces and the stability of nuclei with paired nucleons.

Conclusion

In conclusion, the universe exhibits a highly skewed elemental abundance, dominated by hydrogen and helium. The Oddo-Harkins rule, reflecting the stability of even-numbered nuclei, explains the observed variations in elemental and isotopic abundances. These principles are fundamental to understanding the cosmos and the formation of matter as we know it, providing crucial insights into nucleosynthesis and nuclear physics.

Answer Length

This is a comprehensive model answer for learning purposes and may exceed the word limit. In the exam, always adhere to the prescribed word count.

Additional Resources

Key Definitions

Nucleosynthesis
The process of creating new atomic nuclei from pre-existing nucleons (protons and neutrons). It occurs in stars and during supernova explosions.
Isotopes
Variants of a chemical element which differ in neutron number, and consequently in nucleon number. All isotopes have the same number of protons.

Key Statistics

Approximately 99% of the mass of the solar system is comprised of hydrogen and helium. (Source: NASA, as of knowledge cutoff 2023)

Source: NASA

The abundance of Lithium is approximately 0.0001% by mass in the Earth's crust. (Source: CRC Handbook of Chemistry and Physics, 97th Edition, 2016)

Source: CRC Handbook of Chemistry and Physics

Examples

Stellar Nucleosynthesis in the Sun

The Sun fuses hydrogen into helium in its core through nuclear fusion, releasing vast amounts of energy. This is a prime example of stellar nucleosynthesis.

Frequently Asked Questions

Why is helium the second most abundant element?

Helium was created in significant quantities during the Big Bang, alongside hydrogen. It's also a product of stellar fusion, making it relatively abundant throughout the universe.

Topics Covered

GeochemistryCosmochemistryGeologyCosmic AbundanceIsotopesGeochemical RulesElemental Composition